Solar cells are produced using various methods. The final cells that are embedded on to Solar Panels, are special type of silicon wafer that have gone through a lot of delicate procedures, for increasing the efficiency of the Solar Cell Function.
Before now, silicon was all electrically neutral. Extra electrons were balanced out by the extra protons in the phosphorous of solar cells and missing electrons (holes) were balanced out by the missing protons in the boron. When the holes and electrons mix at the junction between N-type and P-type silicon, however, that neutrality is disrupted. Do all the free electrons fill all the free holes? No. If they did, then the whole arrangement wouldn't be very useful. Right at the junction, however, they do mix and form a barrier, making it harder and harder for electrons on the N side to cross to the P side. Eventually, equilibrium is reached, and we have an electric field separating the two sides.
This electric field acts as a diode, allowing (and even pushing) electrons to flow from the P side to the N side, but not the other way around. It's like a hill -electrons can easily go down the hill (to the N side), but can't climb it (to the P side).
So we've got an electric field acting as a diode in which electrons can only move in one direction. Let's see what happens when light hits the cell.
When light, in the form of photons, hits our solar cells, its energy frees electron-hole pairs.
Each photon with enough energy will normally free exactly one electron, and result in a free hole as well. If this happens close enough to the electric field, or if free electron and free hole happen to wander into its range of influence, the field will send the electron to the N side and the hole to the P side. This causes further disruption of electrical neutrality, and if we provide an external current path, electrons will flow through the path to their original side (the P side) to unite with holes that the electric field sent there, doing work for us along the way. The electron flow provides the current, and the cell's electric field causes a voltage. With both current and voltage, we have power, which is the product of the two.
Single crystal silicon isn't the only material used in Solar cell. Polycrystalline silicon is also used in an attempt to cut manufacturing costs, although resulting solar cells aren't as efficient as single crystal silicon. Amorphous silicon, which has no crystalline structure, is also used, again in an attempt to reduce production costs. Other materials used include gallium arsenide, copper indium diselenide and cadmium telluride. Since different materials have different band gaps, they seem to be "tuned" to different wavelengths, or photons of different energies. One way efficiency has been improved is to use two or more layers of different materials with different band gaps. The higher band gap material is on the surface, absorbing high-energy photons while allowing lower-energy photons to be absorbed by the lower band gap material beneath. This technique can result in much higher efficiencies. Such solar cells, called multi-junction cells, can have more than one.
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